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Mg-Doped CuFeO2 Photocathodes for Photoelectrochemical Reduction of Carbon Dioxide

Author(s): Gu, Jing; Wuttig, Anna; Krizan, Jason W; Hu, Yuan; Detweiler, Zachary M; et al

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dc.contributor.authorGu, Jing-
dc.contributor.authorWuttig, Anna-
dc.contributor.authorKrizan, Jason W-
dc.contributor.authorHu, Yuan-
dc.contributor.authorDetweiler, Zachary M-
dc.contributor.authorCava, Robert J-
dc.contributor.authorBocarsly, Andrew B-
dc.identifier.citationGu, Jing, Wuttig, Anna, Krizan, Jason W, Hu, Yuan, Detweiler, Zachary M, Cava, Robert J, Bocarsly, Andrew B. (2013). Mg-Doped CuFeO2 Photocathodes for Photoelectrochemical Reduction of Carbon Dioxide. The Journal of Physical Chemistry C, 117 (24), 12415 - 12422. doi:10.1021/jp402007zen_US
dc.description.abstractMg-doped CuFeO2 delafossite is reported to be photoelectrochemically active for CO2 reduction. The material was prepared via conventional solid-state methods, and subsequently assembled into an electrode as a pressed pellet. Addition of a Mg2+ dopant is found to substantially improve the conductivity of the material, with 0.05% Mg-doped CuFeO2 electrodes displaying photocathodic currents under visible irradiation. Photocurrent is found to onset at irradiation wavelengths of ∼800 nm with the incident photon-to-current efficiency reaching a value of 14% at 340 nm using an applied electrode potential of −0.4 V vs SCE. Photoelectrodes were determined to have a −1.1 V vs SCE conduction band edge and were found capable of the reduction of CO2 to formate at 400 mV of underpotential. The conversion efficiency is maximized at −0.9 V vs SCE, with H2 production contributing as a considerable side reaction. These results highlight the potential to produce Mg-doped p-type metal oxide photocathodes with a band structure tuned to optimize CO2 reduction.en_US
dc.format.extent12415 - 12422en_US
dc.relation.ispartofThe Journal of Physical Chemistry Cen_US
dc.rightsAuthor's manuscripten_US
dc.titleMg-Doped CuFeO2 Photocathodes for Photoelectrochemical Reduction of Carbon Dioxideen_US
dc.typeJournal Articleen_US

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