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Phase transitions in orthopyroxene (En90) to 49GPa from single-crystal X-ray diffraction

Author(s): Finkelstein, Gregory J; Dera, Przemyslaw K; Duffy, Thomas S

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dc.contributor.authorFinkelstein, Gregory J-
dc.contributor.authorDera, Przemyslaw K-
dc.contributor.authorDuffy, Thomas S-
dc.identifier.citationFinkelstein, Gregory J., Przemyslaw K. Dera, and Thomas S. Duffy. "Phase transitions in orthopyroxene (En90) to 49 GPa from single-crystal X-ray diffraction." Physics of the Earth and Planetary Interiors 244 (2015): 78-86. doi:10.1016/j.pepi.2014.10.009.en_US
dc.description.abstractSynchrotron-based high-pressure single-crystal X-ray diffraction experiments were conducted on ∼Mg0.9Fe0.1SiO3 (En90) orthopyroxene crystals at room temperature to a maximum pressure of 48.5 GPa. The sample was compressed in a diamond anvil cell with a neon pressure-transmitting medium and a gold pressure calibrant. In addition to the previously described orthopyroxene to β-opx transition (designated HPCEN2 in previous studies), we observe two further phase transitions at 29.9 GPa and 40.3 GPa. However, we do not observe the γ-opx phase recently described in an Fe-rich orthopyroxene composition. The structures of both of the new phases were solved in space group Pca21. While their Mg–O layers remain pyroxene-like, their Si–O layers transform in a stepwise fashion to akimotoite-like sheets, with sites in 4-, 4+1-, or 6-fold coordination, depending on the specific structure and layer. Due to the increased Si–O coordination number, we designate the new structures α- and β-post-orthopyroxene (α-popx and β-popx). α-popx has one Si–O layer that is entirely tetrahedral, and one layer that contains both tetrahedra and 4+1-coordinated Si in distorted square pyramids. β-popx retains the mixed 4- and 4+1-coordinated Si layer found in α-popx, while the other Si layer adopts fully octahedral coordination. The α- and β-popx structures show a progressive transformation towards the arrangement of Si layers found in akimotoite, a potentially important phase in the earth’s transition zone. Metastable transformations in pyroxenes are of interest for understanding possible metastability in geological environments such as subducting slabs and meteorite impacts.en_US
dc.format.extent78 - 86en_US
dc.relation.ispartofPhysics of the Earth and Planetary Interiorsen_US
dc.rightsAuthor's manuscripten_US
dc.titlePhase transitions in orthopyroxene (En90) to 49GPa from single-crystal X-ray diffractionen_US
dc.typeJournal Articleen_US

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