Band Structure of the IV-VI Black Phosphorus Analog and Thermoelectric SnSe

I. Pletikosić, F. von Rohr, P. Pervan, P. K. Das, I. Vobornik, R. J. Cava, and T. Valla
Phys. Rev. Lett. 120, 156403 – Published 10 April 2018
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Abstract

The success of black phosphorus in fast electronic and photonic devices is hindered by its rapid degradation in the presence of oxygen. Orthorhombic tin selenide is a representative of group IV-VI binary compounds that are robust and isoelectronic and share the same structure with black phosphorus. We measure the band structure of SnSe and find highly anisotropic valence bands that form several valleys having fast dispersion within the layers and negligible dispersion across. This is exactly the band structure desired for efficient thermoelectric generation where SnSe has shown great promise.

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  • Revised 29 September 2017
  • Received 6 July 2017

DOI:https://doi.org/10.1103/PhysRevLett.120.156403

© 2018 American Physical Society

Physics Subject Headings (PhySH)

Condensed Matter & Materials Physics

Authors & Affiliations

I. Pletikosić1,2,*, F. von Rohr3, P. Pervan4, P. K. Das5,6, I. Vobornik5, R. J. Cava3, and T. Valla2

  • 1Department of Physics, Princeton University, Princeton, NJ 08544, USA
  • 2Condensed Matter and Materials Science Department, Brookhaven National Laboratory, Upton, NY 11973, USA
  • 3Department of Chemistry, Princeton University, Princeton, NJ 08544, USA
  • 4Institut za fiziku, HR-10000 Zagreb, Croatia
  • 5Istituto Officina dei Materiali (IOM-CNR), Laboratorio TASC, I-34149 Trieste, Italy
  • 6International Centre for Theoretical Physics, I-34151 Trieste, Italy

  • *ivop@princeton.edu

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Issue

Vol. 120, Iss. 15 — 13 April 2018

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